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Coal, Diamond, and Man

Ibrahim Ozbek

Sep 1, 2012

All of the physical and chemical conditions of the earth are created in a way to make life possible. The earth's position in the universe and factors like heat, light, water, and air all possess the qualities needed by living beings. This perfection in the macro plan is also the same for elements and molecules in microscopic dimensions.

Carbon atom, which composes nearly 0.2% of the earth's crust, has a very special place among elements. All living beings are formed from carbon-based compounds. In addition, 94% percent of compounds—that is, more than 4 million—contain carbon atoms. Certain carbon compounds form nearly 18% of the matter in living beings. The rest is mostly water. These compounds are used as building blocks in cell formation. Only carbon has the ability of compounding with other elements in sufficient variety and complexities in order to carry out the main functions that life is based on. As carbon atoms easily form chains by making chemical bonds, no other element is given such a quality. These chains formed in a line can separate into branches and can connect to form rings. These rings are actually polygons formed by three, four, five, six, or more carbon atoms. Due to this quality, carbon is the element that forms the basis of many things from the foods we eat, to the clothes we wear, from the fuels we use, to the furniture we have.

The heat level that makes carbon compounds possible is between -20 and +120 0C. Carbon compounds begin freezing at -20 0C and they begin breaking at 120 0C. In space, where extreme heat and freezing cold exists, the only heat range that makes carbon compounds possible is found on earth and this is a very sensitive heat range. Temperatures in our neighboring planets give a better idea: as hot as 450 0C in Venus, and as cold as -53 0C in Mars. Under these temperatures, it is impossible for carbon element to form compounds and thus living beings. Therefore, the earth is the only planet created with the suitable conditions that make life possible.

Crystal structures of carbon atom

Particular repeating arrangement of atoms in three dimensional space to form a certain geometric shape is known as a crystal structure.

Different crystal structures of the same substance are named "allotrope." Carbon has three different allotropes found in nature: amorphous carbon (coal), graphite, diamond. In addition to these, an artificially produced allotrope is fullerene.

Amorphous carbon (coal)

Amorphous structure is one without a definite crystal structure; that is, one where atoms take their places in free order. A mass of carbon atoms of amorphous structure is known as coal. After plants die, they undergo chemical transformation with the activities of microorganisms. If dead plants collect in a suitable wetland and are buried into the ground with a geological process, the carbon amount in their body increases and they begin transforming into coal. Types of coal are categorized according to the carbon percentage they contain. Geologically, this transformation process takes a period of 15 to 345 million years. Coal is one of the most commonly used forms of energy.

Graphite

In graphite, carbon atoms are found in a hexagonal crystal structure. These sheets, resembling the surface of a honeycomb, pile up and form graphite. As the sheets are not connected with firm bonds, they easily shift when some force is applied. This is why graphite is used for eliminating friction at machine industry. The black substance in pencils is graphite hardened by adding some clay. Graphite can resist very high temperatures. Therefore it is used within the steel industry and melting metals. In addition, it is a very good conductor of electricity. For this reason, the brushes of the electric engines in household machines such as a washing machine and a vacuum cleaner are made of graphite. In recent years, graphite has been used as heat shields of space shuttles.

Diamond

Diamond is the hardest natural substance we know. In spite of being a transparent substance and having no color of its own, it can be found in pastel colors such as yellow, brown, or even dim black, owing to being mixed with other minerals. Diamond is a perfect electric isolator and is the substance with highest heat conductivity. For this reason, it can be cut without being deformed. In diamond, carbon atoms are found in a pattern to form a cubical crystal structure. Extraordinary resistance of carbon-carbon bond and its hard and integrated structure prevents its reacting with other things around. It burns at a heat of 850 0C. In a piece of diamond, there can be other atoms that cause impurity and decrease the value. In good quality natural diamonds, there is only 1 alien atom versus 100,000 carbon atoms. In addition to jewelry, diamonds are widely used at industrial products such as drills, glass cutters and the like. 75-80 % of diamond production is used in this industry.

Formation of coal, graphite, or diamond from carbon

Carbon based organic compounds were buried underground as a result of movements by the earth's crust millions of years ago. Physical and chemical changes occurred with those organic masses through heat and pressure. Gradually, water, carbon dioxide, oxygen, and—in the highest phases—hydrogen leaves these masses. This organic matter called "turba" (first transforms into lignite, then to sub bituminous coal, then to bituminous coal, and then to anthracite). If the conditions allow, it transforms into graphite. Coal is the first type of substance formed by carbon atoms on their journey to become diamond. As lower values of heat, pressure, and time suffice for coal formation, graphite requires much higher values. Diamond is formed in the mantle layer of the earth at about 150-200 depth. This valuable substance is later carried to the surface of the earth by volcanic rocks such as lamproite and kimberlite. In order for diamond to form, an atmospheric pressure of 50,000 atm, 2,400 0C of heat, and a period of 3 billion years are required. Without this immense pressure and long time, the substance to be formed by carbon will simply be graphite. It is possible to transform graphite into diamond artificially; however, according to calculations, a minimum pressure of 10,000 atm is required. In 1955, for the first time artificial diamond was obtained under 100,000 atm, 2,500 0C heat, and by using chrome as catalyzer. However, the pieces of diamond obtained were small and black, most of them did not classify as jewels. In another attempt made in 1962, graphite turned into diamond under 200,000 atm, 5,000 0C heat, without using any catalyzer.

The similarity between carbon and human beings

As carbon atoms' properties change according to the crystal structure, people's lifestyle and view of life depends on the community they live in and their position in that community. In order to become diamond, the highest level of its kind, a person needs to undergo hard conditions. If carbon atoms were to say, "this is more than we can bear, we prefer easier conditions," then they can be nothing more than graphite. If the conditions for graphite are avoided as well, then one cannot go beyond the level of coal. Diamonds are kept in safes and worn in most important occasions and graphite has different kinds of practical use as an industrial material. As for coal, it ends up in fire. The situation of human beings in a way resembles carbon atoms. Every person is made of the same elements biologically. Their value will naturally be different, according to the processes they underwent and the behaviors they presented. Some show patience in the face of misfortune, put their sincere trust in God, and become the diamonds of humanity. Some others, whom we can compare to graphite, attain a desirable level even if they cannot become diamonds. Those who choose to assume the lowliest form are likely to face a similar fate with the coal.

References

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  • L. Vlasov, D. Trifonov. 2005. 107 Stories about Chemistry, TUBÝTAK., Ankara.